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Nucleophilic Acylation of o-Quinone Methides: An Umpolung Strategy for the Synthesis of α-Aryl Ketones and Benzofurans.

✍ Scribed by Anita E. Mattson; Karl A. Scheidt


Publisher
John Wiley and Sons
Year
2007
Weight
35 KB
Volume
38
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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Catalytic Additions of Acylsilanes to Im
✍ Anita E. Mattson; Karl A. Scheidt 📂 Article 📅 2005 🏛 John Wiley and Sons ⚖ 25 KB

2005 ## Amines Q 0120 Catalytic Additions of Acylsilanes to Imines: An Acyl Anion Strategy for the Direct Synthesis of α-Amino Ketones. -The title methodology enables direct formation of N-phosphinylated amino ketones and completely avoids benzoin formation. The reaction tolerates structural div