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Nucleophile-assisted cleavage of silane cation radicals

✍ Scribed by Dinnocenzo, Joseph P.; Farid, S.; Goodman, J. L.; Gould, I. R.; Mattes, S. L.; Todd, W. P.

Book ID
121383485
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
437 KB
Volume
111
Category
Article
ISSN
0002-7863

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ChemInform Abstract: Nucleophile-Assiste
ChemInform Abstract: Nucleophile-Assisted Cleavage of Benzyltrialkylsilane Cation Radicals.
✍ K. P. DOCKERY; J. P. DINNOCENZO; S. FARID; J. L. GOODMAN; I. R. GOULD; W. P. TOD πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 26 KB πŸ‘ 2 views

Nucleophile-Assisted Cleavage of Benzyltrialkylsilane Cation Radicals. -The absolute rate constants for the nucleophile-assisted C-Si bond cleavage are determined and the substituent and solvent effects investigated. A SN2 mechanism is discussed as a dominant pathway for the cleavage of the title c