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ChemInform Abstract: Nucleophile-Assisted Cleavage of Benzyltrialkylsilane Cation Radicals.

✍ Scribed by K. P. DOCKERY; J. P. DINNOCENZO; S. FARID; J. L. GOODMAN; I. R. GOULD; W. P. TODD

Publisher
John Wiley and Sons
Year
2010
Weight
26 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

Nucleophile-Assisted Cleavage of Benzyltrialkylsilane Cation Radicals.

-The absolute rate constants for the nucleophile-assisted C-Si bond cleavage are determined and the substituent and solvent effects investigated. A SN2 mechanism is discussed as a dominant pathway for the cleavage of the title cation radicals. -(DOCKERY, K.

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