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ChemInform Abstract: Mechanistic Aspects of β-Bond-Cleavage Reactions of Aromatic Radical Cations

✍ Scribed by Enrico Baciocchi; Massimo Bietti; Osvaldo Lanzalunga


Publisher
John Wiley and Sons
Year
2010
Weight
26 KB
Volume
31
Category
Article
ISSN
0931-7597

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Nucleophile-Assisted Cleavage of Benzyltrialkylsilane Cation Radicals. -The absolute rate constants for the nucleophile-assisted C-Si bond cleavage are determined and the substituent and solvent effects investigated. A SN2 mechanism is discussed as a dominant pathway for the cleavage of the title c