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ChemInform Abstract: Efficient Nucleophilic Cleavage of Oxiranes to Chlorohydrins.

โœ Scribed by C. SARANGI; N. B. DAS; B. NANDA; A. NAYAK; R. P. SHARMA

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
28
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Nucleophile-Assiste
ChemInform Abstract: Nucleophile-Assisted Cleavage of Benzyltrialkylsilane Cation Radicals.
โœ K. P. DOCKERY; J. P. DINNOCENZO; S. FARID; J. L. GOODMAN; I. R. GOULD; W. P. TOD ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 26 KB ๐Ÿ‘ 2 views

Nucleophile-Assisted Cleavage of Benzyltrialkylsilane Cation Radicals. -The absolute rate constants for the nucleophile-assisted C-Si bond cleavage are determined and the substituent and solvent effects investigated. A SN2 mechanism is discussed as a dominant pathway for the cleavage of the title c