ChemInform Abstract: Nucleophile-Assiste
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K. P. DOCKERY; J. P. DINNOCENZO; S. FARID; J. L. GOODMAN; I. R. GOULD; W. P. TOD
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Article
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2010
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John Wiley and Sons
β 26 KB
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Nucleophile-Assisted Cleavage of Benzyltrialkylsilane Cation Radicals. -The absolute rate constants for the nucleophile-assisted C-Si bond cleavage are determined and the substituent and solvent effects investigated. A SN2 mechanism is discussed as a dominant pathway for the cleavage of the title c