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Nucleophile-Assisted Cleavage of Benzyltrialkylsilane Cation Radicals

✍ Scribed by Dockery, Kevin P.; Dinnocenzo, Joseph P.; Farid, Samir; Goodman, Joshua L.; Gould, Ian R.; Todd, William P.


Book ID
127257775
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
238 KB
Volume
119
Category
Article
ISSN
0002-7863

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ChemInform Abstract: Nucleophile-Assiste
✍ K. P. DOCKERY; J. P. DINNOCENZO; S. FARID; J. L. GOODMAN; I. R. GOULD; W. P. TOD πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 26 KB πŸ‘ 2 views

Nucleophile-Assisted Cleavage of Benzyltrialkylsilane Cation Radicals. -The absolute rate constants for the nucleophile-assisted C-Si bond cleavage are determined and the substituent and solvent effects investigated. A SN2 mechanism is discussed as a dominant pathway for the cleavage of the title c