Various algorithms for solving the Solomon equations describing nuclear Overhauser effects (noes) in NMR spectroscopy have been compared. The applicability of the eigenvalue/eigenvector and the numerical integration approaches have been investigated. The eigenvalue/eigenvector approach is not a comp
Nuclear overhauser effects in tritium nmr
β Scribed by Frans M. Kaspersen; Carel W. Funke; Eric M. G. Sperling; Gerard N. Wagenaars
- Publisher
- John Wiley and Sons
- Year
- 1987
- Tongue
- French
- Weight
- 229 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0022-2135
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π SIMILAR VOLUMES
Overlapping resonances in the two-dimensional nuclear Overhauser (NOESY) spectrum of the O-antigenic polysaccharide from Escherichia coli O147 have been resolved by recording a tilted projection of a threedimensional NOESY-HSQC spectrum, where the carbon-13 and proton evolutions are linked together.
The effect of dipole-dipole cross correlations on the net nuclear Overhauser effect (NOE) has been analyzed here for realistic systems by extending the three-spin calculations to four and five spins in order to account for additional cross correlations and spin diffusion. These have been compared wi
## Abstract Direct positive and indirect negative NOEs can often be observed in the same molecule, providing a method for establishing otherwise inaccessible connectivities in complex spectra and an effective probe of conformation in solution.
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