Nuclear magnetic resonance studies of terpenes with chiral and achiral lanthanide(III)-silver(I) binuclear shift reagents
β Scribed by Wenzel, Thomas J.; Sievers, Robert E.
- Book ID
- 123615982
- Publisher
- American Chemical Society
- Year
- 1982
- Tongue
- English
- Weight
- 949 KB
- Volume
- 104
- Category
- Article
- ISSN
- 0002-7863
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A newly developed reversed phase cellulose tris(4-methyl benzoate) known as Chiralcel OJ-R was used to investigate the chiral recognition and enantiomeric separation of eight racemic piperidine-2,6-dione compounds-namely, aminoglutethimide and its major metabolite acetylaminoglutethimide, glutethimi
Binuclear lanthanide(III)-silver(I) f3-diketonate chelates are effective N M R shift and relaxation reagents for substrates containing one or two multiply bonded nitrogen atoms, despite the fact that some of the substrates are able to react with lanthanide chelates alone. The silver cation is bonded