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Binuclear lanthanide(III)–silver(I) NMR shift reagents: Investigations of new achiral and chiral analogs

✍ Scribed by Thomas J. Wenzel; Anne C. Ruggles; Daniel R. Lalonde Jr


Publisher
John Wiley and Sons
Year
1985
Tongue
English
Weight
677 KB
Volume
23
Category
Article
ISSN
0749-1581

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✍ M. Audit; D. Davoust; N. Goasdoue; N. Platzer 📂 Article 📅 1985 🏛 John Wiley and Sons 🌐 English ⚖ 645 KB

Binuclear lanthanide(III)-silver(I) f3-diketonate chelates are effective N M R shift and relaxation reagents for substrates containing one or two multiply bonded nitrogen atoms, despite the fact that some of the substrates are able to react with lanthanide chelates alone. The silver cation is bonded