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Nuclear magnetic resonance spectra and structure of some alkyl vinyl sulphides

✍ Scribed by G. Ceccarelli; E. Chiellini

Publisher
John Wiley and Sons
Year
1970
Tongue
English
Weight
466 KB
Volume
2
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

The NMR spectra of eight alkyl vinyl sulphides have been analyzed and the parameters compared with those obtained from an analogous series of oxygen derivatives. It is shown that a definite parallelism exists between chemical shifts and HH coupling. Difference in absolute values have been explained by mesomeric interaction magnified image involving the ability of sulphur to accommodate a decet of electrons in its valence shell. By analogy with alkyl vinyl ethers, it is possible to predict a similar correlation between the spectral characteristics and relative reactivity of vinyl sulphides in cationic polymerization.

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