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Novel Thermal Reaction of Fischer Carbene Complexes with Imines: Synthesis of β-Methoxy Allylic Amine Derivatives.

✍ Scribed by Kenichiro Sangu; Hirotaka Kagoshima; Kohei Fuchibe; Takahiko Akiyama


Publisher
John Wiley and Sons
Year
2003
Weight
110 KB
Volume
34
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


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✍ Reinhold Zimmer; Hans-Ulrich Reissig 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 28 KB 👁 2 views

Reaction of Cyclooctyne with Fischer Carbene Complexes -Synthesis of Tricyclic Quinone Derivatives. -The Doetz benzannulation reaction of the carbene complexes (I) with the cyclic alkyne (II) is studied. The new tricyclic quinone derivatives (III) are obtained in moderate to good yields indicating t