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ChemInform Abstract: Reaction of Cyclooctyne with Fischer Carbene Complexes — Synthesis of Tricyclic Quinone Derivatives.

✍ Scribed by Reinhold Zimmer; Hans-Ulrich Reissig


Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis


Reaction of Cyclooctyne with Fischer Carbene Complexes -Synthesis of Tricyclic Quinone Derivatives. -The Doetz benzannulation reaction of the carbene complexes (I) with the cyclic alkyne (II) is studied. The new tricyclic quinone derivatives (III) are obtained in moderate to good yields indicating that no particular effects are complicating the Doetz reaction of the strained cyclooctyne. -(ZIMMER, REINHOLD; REISSIG, HANS-ULRICH;


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