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Novel synthesis of the allene moiety of carotenoids via biomimetic photosensitized oxygenation

✍ Scribed by Masayuki Nakano; Noriyuki Furuichi; Hajime Mori; Shigeo Katsumura

Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
67 KB
Volume
42
Category
Article
ISSN
0040-4039

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✦ Synopsis

A novel synthesis of the allene moiety of carotenoids was achieved by the regioselective ene reaction of the vinyl hydrogen rather than the allyl hydrogen of the significantly twisted 1,3-dienes, (3R)-alkoxy-cis-b-ionol derivative, followed by selective allyl rearrangement.

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