✦ LIBER ✦
Synthesis, Crystal Structure, and Catalytic Properties of Novel Dioxidomolybdenum(VI) Complexes with Tridentate Schiff Base Ligands in the Biomimetic and Highly Selective Oxygenation of Alkenes and Sulfides
✍ Scribed by Abdolreza Rezaeifard; Iran Sheikhshoaie; Niaz Monadi; Helen Stoeckli-Evans
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 711 KB
- Volume
- 2010
- Category
- Article
- ISSN
- 1434-1948
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✦ Synopsis
Four novel dioxidomolybdenum(VI) complexes [MoO 2 (L x )-(CH 3 OH)] have been synthesized, using 2[(E)-(2-hydroxy-2phenylethylimino)methyl]phenol derivatives as tridentate ONO donor Schiff base ligands (H 2 L x ) and MoO 2 (acac) 2 . A monoclinic space group was determined by X-ray crystallography from single-crystal data of a sample of these new complexes. The epoxidation of alkenes by using tert-butyl