A novel synthesis of the allene moiety of carotenoids was achieved by the regioselective ene reaction of the vinyl hydrogen rather than the allyl hydrogen of the significantly twisted 1,3-dienes, (3R)-alkoxy-cis-b-ionol derivative, followed by selective allyl rearrangement.
✦ LIBER ✦
The synthesis of the endoperoxide of cyclooctatetraene via photosensitized singlet oxygenation
✍ Scribed by Waldemar Adam; Günter Klug
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- French
- Weight
- 193 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0040-4039
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