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Novel synthesis of 2,3-seco-A-nor-5.alpha.-cholestane-2,3-diol

✍ Scribed by Gust, Devens; Jacobus, John; Mislow, Kurt

Book ID
127043876
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
293 KB
Volume
33
Category
Article
ISSN
0022-3263

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✍ Roberto Bovara; Renato Longhi; Francesco Nicotra; Giuseppe Vecchio 📂 Article 📅 1977 🏛 John Wiley and Sons 🌐 French ⚖ 308 KB

## Abstract (25S)–5α‐cholestane‐3β, 26‐diol [2,4,2′,4′–^3^H~4~] was synthesized by hydrogenation of neotigogenin acetate 2, followed by acetylation to (25S)‐5α‐furostane‐3β, 26‐diol diacetate 5; this was oxidized to (25S)–16–22‐dioxo‐5α‐cholestane‐3β, 26‐diol diacetate 6. Clemmensen reduction of th