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Novel, Short, Stereospecific Synthesis of l yxo -(2 R ,3 R ,4 R )-Phytosphingosine and e rythro -(2 R ,3 S )-Sphingosine †

✍ Scribed by Raghavan, Sadagopan; Rajender, A.


Book ID
127287149
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
83 KB
Volume
68
Category
Article
ISSN
0022-3263

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Novel, efficient and stereospecific synt
✍ Sadagopan Raghavan; A. Rajender; J.S. Yadav 📂 Article 📅 2003 🏛 Elsevier Science 🌐 English ⚖ 350 KB

The stereo-and regioselective elaboration of a bromohydrin from an olefinic precursor and Pummerer ene reaction for carbon carbon bond formation are the key steps in a novel and flexible synthesis of xylo-phytosphingosine and threo-sphingosine.