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Novel, efficient and stereospecific synthesis of xylo-(2R,3S,4S)-phytosphingosine and threo-(2R,3R)-sphingosine

✍ Scribed by Sadagopan Raghavan; A. Rajender; J.S. Yadav

Book ID: 104359929
Publisher: Elsevier Science
Year: 2003
Tongue: English
Weight: 350 KB
Volume: 14
Category: Article
ISSN: 0957-4166
DOI: 10.1016/s0957-4166(03)00427-0

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✦ Synopsis

The stereo-and regioselective elaboration of a bromohydrin from an olefinic precursor and Pummerer ene reaction for carbon carbon bond formation are the key steps in a novel and flexible synthesis of xylo-phytosphingosine and threo-sphingosine.

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