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Novel palladium complexes employing mixed phosphine phosphonates and phosphine phosphinates as anionic chelating [P,O] ligands

✍ Scribed by Reisinger, Corinna M. ;Nowack, Rüdiger J. ;Volkmer, Dirk ;Rieger, Bernhard


Book ID
120828762
Publisher
Royal Society of Chemistry
Year
2007
Tongue
English
Weight
218 KB
Volume
2
Category
Article
ISSN
1477-9226

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The mixed phosphine-phosphine oxides Ph2P(CH2) .-P(O)Ph z (n = 1 or 2) react with KzPtC14 to give cis-{PtC12-[r Treatment of the latter (n --2) with transition metal chloridcs MClz-nH20, or with M%SnC12, SnC14"5H20, Th(NO3)4.xH20 or UO2(NO3)2" 6H20, gives novel heterobimetallic complexes identified