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Heterobimetallic complexes of palladium(II) bridged by the mixed phosphine–phosphine oxide ligand Ph2PCH2CH2P(O)Ph2

✍ Scribed by Subhi A. Al-Jibori; Othman H. Amin; Talal A.K. Al-Allaf; Reg Davis


Book ID
110248288
Publisher
Springer
Year
2001
Tongue
English
Weight
77 KB
Volume
26
Category
Article
ISSN
0340-4285

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Synthesis of novel heterobimetallic comp
✍ Subhi A. Al-Jibori; Ziyad M. Kalay; Talal A. K. Al-Allaf 📂 Article 📅 1994 🏛 Springer 🌐 English ⚖ 263 KB

The mixed phosphine-phosphine oxides Ph2P(CH2) .-P(O)Ph z (n = 1 or 2) react with KzPtC14 to give cis-{PtC12-[r Treatment of the latter (n --2) with transition metal chloridcs MClz-nH20, or with M%SnC12, SnC14"5H20, Th(NO3)4.xH20 or UO2(NO3)2" 6H20, gives novel heterobimetallic complexes identified