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Novel Organic–Inorganic Layered Compounds Derived from Simple Coordination Building Blocks: Synthesis and Structural Characterization of (H3NCH2CH2NH3)[Fe(C2O4)MoO4] and Fe(H2NCH2CH2NH2)MoO4

✍ Scribed by Songping D. Huang; Yongkui Shan

Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
501 KB
Volume
152
Category
Article
ISSN
0022-4596

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✦ Synopsis

Two new hybrid organic+inorganic compounds (H 3 NCH 2 CH 2 NH 3 )[Fe(C 2 O 4 )MoO 4 ] (1) and Fe(H 2 NCH 2 CH 2 NH 2 ) (2) were synthesized by the hydrothermal reaction between Fe(C 2 O 2 ) ' 2H 2 O, molybic acid, and ethylenediamine. The structure of 1 consists of 2-D layers formed by [Fe(C 2 O 4 )MoO 4 ] 2؊ nets with H 3 N ؉ CH 2 CH 2 N ؉ H 3 dications situated in the gaps. The structure of 2 features a double-layered structure formed by FeMoO 4 units that are capped by cis-coordinated H 2 NCH 2 CH 2 NH 2 molecules.

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