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Synthesis and Characterization of a New Zinc Phosphate, [NH3(CH2)4NH3]2+[Zn2P3O9(OH)3]2−, Containing Alternating Inorganic–Organic Layers

✍ Scribed by Srinivasan Natarajan; Martin P. Attfield; Anthony K. Cheetham

Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
839 KB
Volume
132
Category
Article
ISSN
0022-4596

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✦ Synopsis

The structure consists of alternating inorganic and organic layers. The inorganic layers are held together by strong hydrogen bonding, creating cavities in which diprotonated diaminobutane molecules reside.

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Two New 1,3-Diammonium-Propane Zinc Hydr
Two New 1,3-Diammonium-Propane Zinc Hydrogen Phosphates: H3N(CH2)3NH3·Zn2(HPO4)2(H2PO4)2, with 12-Ring Layers, and H3N(CH2)3NH3·Zn(HPO4)2, with 4-Ring Ladders
✍ William T.A. Harrison; Zsolt Bircsak; Lakshitha Hannooman; Zhenghua Zhang 📂 Article 📅 1998 🏛 Elsevier Science 🌐 English ⚖ 312 KB

The solution-mediated syntheses, single-crystal structures, and some physical properties of the first 1,3-diammonium-propane zinc phosphates, H 3 N(CH 2 ) 3 NH 3 • Zn 2 (HPO 4 ) 2 (H 2 PO 4 ) 2 and H 3 N(CH 2 ) 3 NH 3 • Zn(HPO 4 ) 2 , are described. Both phases contain vertex-sharing ZnO 4 and (H 2