Novel MoFeS Clusters from [(C5Me5)2Mo2S4] and Fe(CO)5 or Fe2(CO)9
โ Scribed by Prof. Dr. Henri Brunner; Norbert Janietz; Dr. Joachim Wachter; Dipl.-Chem. Thomas Zahn; Prof. Dr. Manfred L. Ziegler
- Publisher
- John Wiley and Sons
- Year
- 1985
- Tongue
- English
- Weight
- 319 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Reaction of equimolar amounts of the ferriophosphaalkene P; M = Al (2a), Ga (3a), In (4a) and E = As; M = Al (2b), Ga (3b), and In (4b). These compounds feature ฮท 1 -coordination [(ฮท 5 -C 5 Me 5 )(CO) 2 FeP=C(NMe 2 ) 2 ] (1a) or the ferrioarsaalkene [(ฮท 5 -C 5 Me 5 )(CO) 2 FeAs=C(NMe 2 ) 2 ] (1b) wi
The anionic clusters [Fe 5 MN(CO) 14 Cp] 2-[M = Mo (1) or W (2)] were synthesized from [Fe 4 N(CO) 12 ] -and [MCp(CO) 3 ] - in refluxing acetonitrile. The clusters [Fe 3 M 3 N(CO) 18 ] 3-[M = Mo (3) or W (4)] were prepared by reaction of [Fe 4 N(CO) 12 ] - with [M 2 (CO) 10 ] 2-under the same condit