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Novel MoFeS Clusters from [(C5Me5)2Mo2S4] and Fe(CO)5 or Fe2(CO)9

โœ Scribed by Prof. Dr. Henri Brunner; Norbert Janietz; Dr. Joachim Wachter; Dipl.-Chem. Thomas Zahn; Prof. Dr. Manfred L. Ziegler


Publisher
John Wiley and Sons
Year
1985
Tongue
English
Weight
319 KB
Volume
24
Category
Article
ISSN
0044-8249

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The anionic clusters [Fe 5 MN(CO) 14 Cp] 2-[M = Mo (1) or W (2)] were synthesized from [Fe 4 N(CO) 12 ] -and [MCp(CO) 3 ] - in refluxing acetonitrile. The clusters [Fe 3 M 3 N(CO) 18 ] 3-[M = Mo (3) or W (4)] were prepared by reaction of [Fe 4 N(CO) 12 ] - with [M 2 (CO) 10 ] 2-under the same condit