The first 1,5-dioxa-4l 4 -telluraspiro[3.3]heptane was synthesized and its structure was determined by X-ray analysis. This tellurane gave the corresponding oxirane and olefin, as well as alcohol, upon heating, which were shown to be formed via a radical pathway.
Novel formation of 4-methylthiopyrene in a Hofmann elimination reaction directed toward the synthesis of 17,19-dioxa[2.2.3](1,2,3)cyclophanediene
β Scribed by Lai, Yee-Hing; Eu, Hong-Leng
- Book ID
- 121467811
- Publisher
- Royal Society of Chemistry
- Year
- 1993
- Weight
- 549 KB
- Volume
- 2
- Category
- Article
- ISSN
- 1472-7781
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
A small variation in the vanadium reagent leads to a completely different product: The cyclooligomerization of phosphaalkynes 2 with tBuN=VCl β DME (DME=1,2-dimethoxyethane) proceeds with incorporation of the imido fragment to give the azatetraphosphaquadricyclanes 1. In contrast, with the correspond