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Synthesis, structure, and thermolysis of a novel spirotellurane bearing two 1,2-oxatelluretane rings, 1,5-dioxa-4λ4-telluraspiro[3.3]heptane: oxirane and olefin formation reactions

✍ Scribed by Naokazu Kano; Tatsuhisa Takahashi; Takayuki Kawashima

Publisher: Elsevier Science
Year: 2002
Tongue: French
Weight: 105 KB
Volume: 43
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(02)01527-7

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✦ Synopsis

The first 1,5-dioxa-4l 4 -telluraspiro[3.3]heptane was synthesized and its structure was determined by X-ray analysis. This tellurane gave the corresponding oxirane and olefin, as well as alcohol, upon heating, which were shown to be formed via a radical pathway.

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