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Novel epimerizatton of steroidal allylic alcohols

โœ Scribed by Mori Makoto; Ikegami Shiro; Tamaoki Bun-ichi


Book ID
118978571
Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
589 KB
Volume
33
Category
Article
ISSN
0039-128X

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Further studies on the selective oxidati
โœ Edward J. Parish; Aubrey D. Scott; James R. Dickerson; Waite Dykes ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 264 KB

Certain aromatic amines, when used in conjunction with pyridinium chlorochromate, have been found to selectively oxidize the allylic hydroxyl group of steroidal alcohols to the corresponding a,/~-unsaturated ketones. In this respect, the amines 2,2'-bipyridine, 2,4,6-Iriphenylpyridinine, pyrazine, p