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Novel electron impact-induced hydrogen rearrangements in the mass spectra of organorhenium hydrides and alkyls

✍ Scribed by Guy L. Crocco; Thomas R. Sharp; John A. Gladysz


Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
293 KB
Volume
73
Category
Article
ISSN
0168-1176

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Electron-impact-induced hydrogen migrati
✍ D. V. Ramana; M. Vairamani; S. Kala 📂 Article 📅 1975 🏛 John Wiley and Sons 🌐 English ⚖ 198 KB

## Abstract Substited pivalanilides give rise to fragments corresponding to anilies on electron‐impact, which is due to the migration of a hydrogen atom from the __t__‐butyl group to the nitrogen. The Hammett correlation indicates that the formation of this fragment is favoured by electron‐donating