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Skeletal and hydrogen rearrangements in the electron impact mass spectrum of propene

โœ Scribed by Alex. G. Harrison; Paul P. Dymerski


Publisher
John Wiley and Sons
Year
1977
Tongue
English
Weight
347 KB
Volume
12
Category
Article
ISSN
1076-5174

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Mass spectral hydrogen rearrangements of
โœ Joseph Deutsch; Miriam Chriki ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 239 KB

## Abstract 1,1โ€ฒโ€Bicycloalkylโ€2,2โ€ฒโ€diols (mixtures of stereoisomers) and 1,1โ€ฒโ€diols on electron impact give rise to strong peaks equivalent to [Mโ€1]^+^ions, corresponding to cycloalkenone fragments and obviously involving hydrogen atom migrations. Deuterium labelling and substitution techniques rev