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Electron-impact-induced rearrangements in the mass spectra of phosphinyl stabilized triphenylphosphonium ylides

✍ Scribed by Lászlo Tökés; Gordon H. Jones

Publisher
John Wiley and Sons
Year
1975
Tongue
English
Weight
426 KB
Volume
10
Category
Article
ISSN
1076-5174

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Electron-impact-induced hydrogen migrati
Electron-impact-induced hydrogen migration in organic molecules I–Substituent effects in the mass spectra of pivlanilides
✍ D. V. Ramana; M. Vairamani; S. Kala 📂 Article 📅 1975 🏛 John Wiley and Sons 🌐 English ⚖ 198 KB

## Abstract Substited pivalanilides give rise to fragments corresponding to anilies on electron‐impact, which is due to the migration of a hydrogen atom from the __t__‐butyl group to the nitrogen. The Hammett correlation indicates that the formation of this fragment is favoured by electron‐donating