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Novel C 2 -Symmetric Planar Chiral Diphosphine Ligands and Their Application in Pd-Catalyzed Asymmetric Allylic Substitutions

✍ Scribed by Liu, Delong; Xie, Fang; Zhang, Wanbin


Book ID
126322838
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
161 KB
Volume
72
Category
Article
ISSN
0022-3263

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An efficient and flexible asymmetric synthesis of planar chiral ferrocenyl ligands bearing a stereogenic centre at the Ξ²-position to the metallocene backbone is described. A variety of donor groups can be independently introduced as electrophiles, thus allowing electronic and steric fine-tuning of t