✦ LIBER ✦

C 2 -Symmetric Diphosphine Ligands with Only the Planar Chirality of Ferrocene for the Palladium-Catalyzed Asymmetric Allylic Alkylation

✍ Scribed by Zhang, Wanbin; Shimanuki, Takashi; Kida, Toshiyuki; Nakatsuji, Yohji; Ikeda, Isao

Book ID: 127248246
Publisher: American Chemical Society
Year: 1999
Tongue: English
Weight: 70 KB
Volume: 64
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo9902998

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

ChemInform Abstract: C2-Symmetric Diphos

ChemInform Abstract: C2-Symmetric Diphosphine Ligands with only the Planar Chirality of Ferrocene for the Palladium-Catalyzed Asymmetric Allylic Alkylation.

✍ Wanbin Zhang; Takashi Shimanuki; Toshiyuki Kida; Yohji Nakatsuji; Isao Ikeda 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB 👁 2 views

Novel C2-symmetric diphosphine ligand wi

Novel C2-symmetric diphosphine ligand with only the planar chirality of ferrocene

✍ Wanbin Zhang; Toshiyuki Kida; Yohji Nakatsuji; Isao Ikeda 📂 Article 📅 1996 🏛 Elsevier Science 🌐 French ⚖ 313 KB

ChemInform Abstract: Novel C2-Symmetric

ChemInform Abstract: Novel C2-Symmetric Diphosphine Ligand with Only the Planar Chirality of Ferrocene.

✍ W. ZHANG; T. KIDA; Y. NAKATSUJI; I. IKEDA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 29 KB 👁 2 views

ChemInform Abstract: A New C2-Symmetric

ChemInform Abstract: A New C2-Symmetric Chiral Diphosphine Ligand: Palladium-Catalyzed Enantioselective Allylic Alkylation of Cycloalkenyl Substrate.

✍ Akihito Saitoh; Mie Misawa; Toshiaki Morimoto 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 29 KB 👁 2 views

ChemInform Abstract: Palladium-Catalyzed

ChemInform Abstract: Palladium-Catalyzed Asymmetric Allylic Alkylations Using Diphenylphosphino(oxazolinyl)ferrocene Ligands: Effects of Planar Chirality on the Reactivity and Selectivity.

✍ K. H. AHN; C.-W. CHO; J. PARK; S. LEE 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB 👁 1 views

Synthesis of novel planar chiral ferroce

Synthesis of novel planar chiral ferrocene and cyclopentadienyl manganese tricarbonyl derivatives and their use as chiral ligands in the palladium-catalyzed asymmetric allylic alkylation

✍ Jae Hoon Lee; Seung Uk Son; Young Keun Chung 📂 Article 📅 2003 🏛 Elsevier Science 🌐 English ⚖ 243 KB

We have shown that cymantrene derivatives are better P,N-chelate ligands for palladium-catalyzed allylic alkylation than ferrocenes, which have a similar pentagonal ligand structure to cymantrene derivatives. In particular, the PPh 3 -substituted cymantrene gave a higher enantioselectivity (>98%).