Novel approach to synthesis of β-Hydroxyphosphonic acids
✍ Scribed by Yaremchuk, I. O.; Kolodyazhnyi, O. I.; Muzychka, L. V.; Smolii, O. B.
- Book ID
- 121552872
- Publisher
- Springer
- Year
- 2014
- Tongue
- English
- Weight
- 163 KB
- Volume
- 84
- Category
- Article
- ISSN
- 1070-3632
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📜 SIMILAR VOLUMES
Treatment of carbohydrate-derived g-hydroxyphosphonic acids under usual acetylation conditions affords the corresponding phostones in good yield. The method could be used for the preparation of free phostones as well as aand b-phosphonomethylarabinose.
## Abstract For Abstract see ChemInform Abstract in Full Text.
Low-valent cobalt complexes were used in Reformat&y-type additions of a-halophosphonates to carbonyl compounds (ketones and aldehydes) to yield a variety of P-hydroxyphosphonates.