Novel antiferromagnetic dinuclear complexes of nickel(II), manganese(II) and cobalt(II) with diphenato as bridging ligand: Synthesis, spectra and magnetism
✍ Scribed by Jian Gao; Shu-Lin Ma; Cheng-Yong Jin; Dai-Zheng Liao
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 372 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0277-5387
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## Abstract Three azido‐bridged Mn^II^ complexes of formulas [Mn~2~(N~3~)~4~(ttp)~2~] (1), [Mn~2~(N~3~)~4~(ttp‐N~3~)~2~] (2) and [Mn~2~(N~3~)~4~(ttp‐N~3~)~2~]~3~[Mn^III^(ttp‐N~3~)(N~3~)~3~]~2~ (3), where ttp and ttp‐N~3~ represent 4′‐__p__‐tolyl‐2,2′:6′,2″‐terpyridine and 4′‐__p__‐azidomethylphenyl
## Abstract Two novel binuclear nickel(II) and cobalt(III) complexes with two or three dissimilar bridges, [Ni~2~(tacn)~2~(__μ__‐N~3~)~2~(__μ__‐O~2~CPh)](ClO~4~)⋅H~2~O (1) and [Co~2~(tacn)~2~(__μ__‐N~3~)(__μ__‐OH)(__μ__‐O~2~CPh)](ClO~4~)~3~ (2) (tacn=1,4,7‐triazacyclononane), were synthesized and s