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Novel amine-catalysed hydroalkoxylation reactions of activated alkenes and alkynes

✍ Scribed by Murtagh, Julie E.; McCooey, S�amus H.; Connon, Stephen J.

Book ID
119948743
Publisher
Royal Society of Chemistry
Year
2005
Tongue
English
Weight
256 KB
Volume
2
Category
Article
ISSN
1359-7345

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✍ M. A. KAZANKOVA; I. G. TROSTYANSKAYA; I. V. EFIMOVA; I. P. BELETSKAYA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 32 KB 👁 2 views

The base mediated reactions of alkenyl alkyl ethers (cf. (I), (III), ( V)) as well as ketene acetals (VII) with phosphorus trihalides result in the unprecedented electrophilic substitution of a vinylic hydrogen by a dihalogenophosphine group furnishing (alkoxyalkenyl) dihalogenophosphines in good yi