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Reactions of N-substituted arylsulfilimines with acylating agents and with activated halobenzenes, alkynes, and alkenes

✍ Scribed by Tamura, Yasumitsu; Sumoto, Kunihiro; Matsushima, Hiroshi; Taniguchi, Hiroshi; Ikeda, Masazumi


Book ID
126212135
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
690 KB
Volume
38
Category
Article
ISSN
0022-3263

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ChemInform Abstract: Electrophilic React
✍ M. A. KAZANKOVA; I. G. TROSTYANSKAYA; I. V. EFIMOVA; I. P. BELETSKAYA πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 32 KB πŸ‘ 2 views

The base mediated reactions of alkenyl alkyl ethers (cf. (I), (III), ( V)) as well as ketene acetals (VII) with phosphorus trihalides result in the unprecedented electrophilic substitution of a vinylic hydrogen by a dihalogenophosphine group furnishing (alkoxyalkenyl) dihalogenophosphines in good yi