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ChemInform Abstract: Transformations of Nitro-Substituted Dihydroisoindoles in Reactions with Activated Alkynes.

✍ Scribed by L. G. Voskressensky; L. N. Kulikova; A. V. Kleimenov; N. I. Guranova; A. V. Listratova; A. V. Varlamov


Publisher
John Wiley and Sons
Year
2011
Weight
22 KB
Volume
42
Category
Article
ISSN
0931-7597

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The base mediated reactions of alkenyl alkyl ethers (cf. (I), (III), ( V)) as well as ketene acetals (VII) with phosphorus trihalides result in the unprecedented electrophilic substitution of a vinylic hydrogen by a dihalogenophosphine group furnishing (alkoxyalkenyl) dihalogenophosphines in good yi