Note on Bimolecular Reactions.
โ Scribed by Friedman, H. B.; Fulmer, H. K.
- Book ID
- 126817990
- Publisher
- American Chemical Society
- Year
- 1930
- Tongue
- English
- Weight
- 122 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
A simple model for the steric factor in bimolecular reactions is developed. The assumptions are identified which underlie an earlier result of Pelzer and Wigner and of Johnston, when one of the reagents is an atom. The treatment is then extended to reactions between two molecules. In each case it is
We examine the overall behavior of a mixture in which nonuniformly coupled bimolecular reactions proceed at comparable rates. Using a regular perturbation method, we derive approximate equations governing the behavior of the reactant lump in a plug-flow or batch reactor. We show that overall second-