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Norbornadiene(bipyridyl)molybdenum(II) Complexes: Synthesis, Structure and Reactivity of [Mo(CO)(C7H8)(C10H6R2N2)X2] (X = I, Br)

✍ Scribed by Daniel, Thomas ;Nagao, Hirotaka ;Tanaka, Koji ;Nakamura, Akira


Publisher
Wiley (John Wiley & Sons)
Year
1995
Tongue
English
Weight
738 KB
Volume
128
Category
Article
ISSN
0009-2940

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To a stirred solution of [TiC13(trimpsi)(thf)] (3.90 g, 7.27 mmol) in tetrahydrofuran (50 mL) at -78Β°C was added naphthalenesodium (150 mL, 0.145 M in THF, 21.8 mmol). A red-purple solution formed immediately. The solution was warmed to room temperature slowly, and the solvent was removed in vacuum.