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Nonelectrolyte Solvation in Aqueous Dimethyl Sulfoxide—A Calorimetric and Infrared Spectroscopic Study

✍ Scribed by G. Reza Bebahani; David Dunnion; Patrick Falvey; Kenneth Hickey; Mary Meade; Yvonne McCarthy; Martyn C. R. Symons; W. Earle Waghorne

Book ID
110220406
Publisher
Springer US
Year
2000
Tongue
English
Weight
318 KB
Volume
29
Category
Article
ISSN
0095-9782

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✍ Martyn C.R. Symons; Graham Eaton 📂 Article 📅 1981 🏛 Elsevier Science 🌐 English ⚖ 157 KB

Studies of the C=O suetchmg mode of acetone in fluid aqueous solutions suggest that water forms two hydrogen bonds to each oxygen atom. In marked contrast, acetone in frozen solutions is endathrated by water, there being no hydrogen bonds to the carboxy oxygen. Reasons for this contxast are discusse