✦ LIBER ✦

Nonaqueous oxidation of nucleoside phosphites to the phosphates

✍ Scribed by Y. Hayakawa; M. Uchiyama; R. Noyori

Book ID: 104219026
Publisher: Elsevier Science
Year: 1986
Tongue: French
Weight: 273 KB
Volume: 27
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)84946-1

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✦ Synopsis

Summay : Bis (trimethylsilyl) peroxide, t-butyl hydroperoxide, cumene hydroperoxide, and N-methylmorpholine N-oxide serve as excellent agents for anhydrous oxidation of nucleoside phosphites to the phosphates.

The reaction using bis (trimethylsilyl) peroxide is conspicuously accelerated by added trimethylsilyl triflate or Nafion-TMS.

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