Nonacarbonyl-μ3-N,N-diethyldithiocarbamato-κ3S:S:S′-μ-hydrido-triosmium(3 Os—Os)
✍ Scribed by Garcia-Orozco, Ivan ;Pastor, Cesar J. ;Souto, Beatriz ;Delgado, Esther ;Hernández, Elisa ;Alvarez-Toledano, Cecilio
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 143 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 223 K Mean '(C±C) = 0.005 A Ê R factor = 0.041 wR factor = 0.100 Data-to-parameter ratio = 25.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the crystal structure of the title compound, [Cu(NCS)-(C 4 H 3 IN 2 )] n , each Cu atom is coordinated by three thiocyanate anions and one 2-iodopyrazine ligand within a distorted tetrahedron. The Cu-coordinated units form dimers, which are connected into layers by the thiocyanate anions.
tris-[(N,N,N 0 0 0 ,N 0 0 00 0 0 ,N 0 0 00 0 0 -pentamethyldiethylenetriaminej 3 N,N 0 0 0 ,N 0 0 00 0 0 )zinc(II)] tris(perchlorate) Jaromı ´r Marek, a,b \* Zdene ˇk Tra ´vnı ´c ˇek b and S ˘a ´rka C ˇerma ´kova ´b