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Nona­carbonyl-μ-hydrido-(μ3,η2-triiso­propyl­silyl­ethynyl)triruthenium

✍ Scribed by Delgado, E. ;Donnadieu, B. ;Hernandez, E. ;Martin, M. Paz ;Zamora, F.

Publisher
International Union of Crystallography
Year
2002
Tongue
English
Weight
173 KB
Volume
58
Category
Article
ISSN
1600-5368

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✦ Synopsis

The structure of the title compound, [Ru 3 (CO) 9 ("-H)(" 3 -C 2 Si i Pr 3 )], consists of an almost equilateral triangular Ru 3 core, with the acetylide ligand '-bonded to one Ru atom and %-bonded to the other two Ru atoms. The hydride atom is located between the two Ru atoms that are %-bonded to the acetylide. Three terminal carbonyls around each ruthenium atom complete the structure.

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