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(η6-Benzene)­bis(η6-p-cymene)­tri-μ-hydrido-μ3-oxo-triruthenium hexa­fluoro­phosphate

✍ Scribed by Vieille-Petit, Ludovic ;Therrien, Bruno ;Süss-Fink, Georg


Publisher
International Union of Crystallography
Year
2003
Tongue
English
Weight
151 KB
Volume
59
Category
Article
ISSN
1600-5368

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✦ Synopsis


The trinuclear arene±ruthenium cluster cation [H 3 Ru 3 ( 6 -C 6 H 6 )( 6 -C 6 H 4 MePr i -p) 2 (" 3 -O)] + has been synthesized and crystallized as the hexa¯uorophosphate salt. The cation possesses a mirror plane through the ( 6 -benzene)ruthenium moiety and the " 3 -O atom, and is disordered over a perpendicular mirror plane that includes the three Ru atoms.


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