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Non-wittig type reaction of tebbe reagent with acyl chloride

✍ Scribed by Ta-Shue chou; Sung-Ben Huang

Publisher: Elsevier Science
Year: 1983
Tongue: French
Weight: 126 KB
Volume: 24
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)81873-0

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✦ Synopsis

Reactions between Tebbe reagent and acyl chlorides proceeded in non-Wittig type manner, giving the corresponding methyl ketones. A possible reaction mechanism is discussed.

Recently, biscyclopentadienyl titanium-p-chloro-p-methylidene bismethyl aluminum 1 ( Tebbe reagent ) and its aluminum free analogues have received considerable attention 2-6 -

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