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Non-linear effects on solvation dynamics

โœ Scribed by Akira Yoshimori

Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
401 KB
Volume
184
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

We study the non-linear effects on the dynamical process of the salvation in a polar solvent. On the basis of the non-linear generalized Smoluchowski equation with the linear-response free energy, we calculate the time dependence of the solvent-solute interaction. It is shown that the salvation process becomes slow in the long-time region where the non-linear coupling between the dynamics of the solvent number density and the orientational relaxation is significant.

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