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Non-ideality in vinyl polymerization—V. Polymerization of methylmethacrylate in benzene initiated by azo-bisisobutyronitrile

✍ Scribed by P.C. Deb; S.K. Kapoor

Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
296 KB
Volume
15
Category
Article
ISSN
0014-3057

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Non-ideality in vinyl polymerization—IV.
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Vinyl acetate was polymerized in bulk and in benzene at 50°C using a wide range of concentrations of azobisisobutyronitrile. Values offk (the efficiency of initiator) and kr,,/klk p (the characteristic constant of primary radical termination) were found to be 0.53 and 2.00 x 104 respectively from da

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Detailed kinetic analysis of AIBN-initiated polymerization of methylmethacrylate in presence of p-benzoquinone has been reported. Primary radical transfer, whereby a primary radical transfers its radical reactivity to a transfer agent, has been considered along with macroradical transfer. It is foun

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The kinetics of vinyl chloride polymerization initiated by benzoyl peroxide doubly labelled with t4C and 3H were studied in 1,2-dichloroethane solution at 60 °. The importance of primary radical termination in the polymerization is examined by kinetic analysis and by analysis of polymers for combine