## Abstract Es wird die Kinetik der Polymerisation von Vinylmonomeren in wΓ€Γriger LΓΆsung beschrieben, die bei PhotoβIntiierung durch die Radikale C~2~O~4~^Β·β^ und HCitr^Β·β^ aus den Ionenpaaren FeC~2~O~4~+ und FeHCitr^+^ erfolgt. Γber die spektrophotometrischen Untersuchungen der Formeln und Stabili
Kinetics of vinyl polymerization initiated by ceric ion in aqueous solution
β Scribed by V. S. Ananthanarayanan; M. Santappa
- Publisher
- John Wiley and Sons
- Year
- 1965
- Tongue
- English
- Weight
- 704 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0021-8995
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The micellar effect on the kinetics of ceric ion-initiated polymerization of acrylonitrile (AN) in the presence of N-acetylglycine has been studied in the temperature range 30- 50Β°C. The neutral emulsifier (Triton X-100) has no effect on the Rp, whereas both anionic (NaLS) and cationic (NCTAB) emuls
## Abstract It is found that acetoacetanilide (system. name: __N__βphenylβ3βoxobutanamide) possesses a very high reactivity towards ceric ions, Ce^4+^, in initiating the polymerization of vinyl monomers. In the presence of acetoacetanilide, the rate of the acrylamide polymerization is larger by a f