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Non-Arrhenius temperature dependence of the rate constant for the H + H2S reaction

✍ Scribed by Masabumi Yoshimura; Mitsuo Koshi; Hiroyuki Matsui; Kenshu Kamiya; Hideaki Umeyama


Book ID
107735412
Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
560 KB
Volume
189
Category
Article
ISSN
0009-2614

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πŸ“œ SIMILAR VOLUMES


Temperature dependence of the rate const
✍ C. L. Lin πŸ“‚ Article πŸ“… 1982 πŸ› John Wiley and Sons 🌐 English βš– 274 KB πŸ‘ 2 views

## Abstract Absolute rate constants for the reaction of OH with H~2~S have been measured over the temperature range of 239–425 K using the flash photolysis–resonance fluorescence technique. The results showed that the rate constants deviate slightly from Arrhenius behavior but can still be represen

Temperature dependence of the rate const
✍ Marcin Buchowiecki πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons 🌐 English βš– 176 KB

## Abstract Rate constant ratios __k__(__T__)/__k__(1,500K) for two symmetrical reactions H^βˆ’^ + H~2~ β†’ H~2~ + H^βˆ’^ and H^+^ + H~2~ β†’ H~2~ + H^+^ are reported. Direct method based on quantum instanton approximation for evaluation of the temperature dependence of the quantum‐mechanical reaction rate

Temperature dependence of the rate const
✍ Yu-Lin Lin; Niann-Shiah Wang; Yuan-Pern Lee πŸ“‚ Article πŸ“… 1985 πŸ› John Wiley and Sons 🌐 English βš– 699 KB

The rate constants of the reaction between OH and H2S in He, N,, and O2 over the temperature range 245-450 K have been determined using the discharge flow-resonance fluorescence technique. At 299 K, kl = (4.4 ? 0.7) x lo-'' cm3 molecule-' S K I . T h e t e m p e r a t u r e dependence of t h e r a