N,N-Dimethyl-1-phenylsulfonyl-1H-pyrrole-3-sulfonamide
✍ Scribed by Grossie, David A. ;Malwitz, David J. ;Ketcha, Daniel M.
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 122 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title molecule, C 21 H 17 NO 3 S 2 , the sulfonyl-bound and sulfinyl-bound phenyl rings form dihedral angles of 82.04 (5) and 26.26 (8) , respectively, with the indole ring system. In the crystal structure C-HÁ Á ÁO, C-HÁ Á Á andinteractions form a two-dimensional network.
The title compound, C~18~H~15~N~3~O, was prepared from phenyl(1__H__-pyrrol-2-ylmethylene)amine and phenyl isocyanate in the presence of catalytic amounts of [Pd(PPh~3~)~4~]. The conformation of the molecular structure is determined by an intramolecular hydrogen bond between the amide NH function an
In the title compound, C 16 H 15 NO 2 S, the indole group is planar and approximately perpendicular to the sulfonyl-bound phenyl ring; the dihedral angle between the planes is 86.80 (6) . The molecules form centrosymmetric dimers via C-HÁ Á ÁO hydrogen bonds.
In the title compound, C~21~H~15~NO~3~S~2~, the phenyl ring of the phenylsulfonyl substituent makes a dihedral angle of 73.6 (1)° with the mean plane of the indole ring system, whereas the phenyl ring of the phenylsulfanyl group forms a dihedral angle of 73.9 (1)° with the mean plane of the indole r