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N-Phenyl-2-(phenyliminomethyl)pyrrole-1-carboxamide

✍ Scribed by Imhof, Wolfgang


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
671 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


The title compound, C~18~H~15~N~3~O, was prepared from phenyl(1__H__-pyrrol-2-ylmethylene)amine and phenyl isocyanate in the presence of catalytic amounts of [Pd(PPh~3~)~4~]. The conformation of the molecular structure is determined by an intramolecular hydrogen bond between the amide NH function and the imine N atom. The molecule is essentially planar. Only the peripheral phenyl substitutents are bent out of the plane.


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